توجه: محتویات این صفحه به صورت خودکار پردازش شده و مقاله‌های نویسندگانی با تشابه اسمی، همگی در بخش یکسان نمایش داده می‌شوند.
۱Simulation of Dissolution Process of Hydrophobic Coated Core– Shell Particles at Interface of Two Immiscible Fluids
نویسنده(ها): ، ،
اطلاعات انتشار: هفتمین کنگره ملی مهندسی شیمی، سال
تعداد صفحات: ۱۰
The main purpose of this paper is modeling and simulation of in–situ releasing of the nano size polymeric core and shell particle in the interface of two immiscible fluids. When these particles reach at the organic–aqueous interface the hydrophobic coating layer starts dissolving into the organic phase. After removing of the coat, the main inside polymer which is not soluble in the organic phase starts to diffuse back into the aqueous phase and increase the viscosity of theaqueous phase. In this paper, the governing equations of the process are obtained and numerically solved. The coating dissolution is considered as spherical diffusion followed by polymer chain disentanglement through a diffusion boundary layer. Moreover, a swellable–chain disentanglementmodel and concentration–dependent diffusion coefficient is considered for inside polymer dissolution into the aqueous phase which leads to a nonlinear partial differential equation with two moving boundries at both sides. Using finite difference scheme, the governing equation arenumerically solved by defining some dimensionless parameters for the main parameters as well as the moving boundaries. Finally, a sensitivity analysis is performed for investigating the impact of different parameters affecting the dissolution process<\div>
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